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    <title>UTas ePrints - Organomercury Compounds XI. Some Coordination Derivatives of Bispentafluorophenylmercury</title>
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    <meta content="Canty, A.J." name="eprints.creators_name" />
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<meta content="Allan.Canty@utas.edu.au" name="eprints.creators_id" />
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<meta content="Organomercury Compounds XI. Some Coordination Derivatives
of Bispentafluorophenylmercury

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<meta content="The oomplexes (C6F5)2HgL (L = 4,4'-dimethyl-2,2'-bipyridyl, 2,2'-biquinolyl, 2,2':6',2&quot;-terpyridyl, 2,4,7,9-tetramethyl-1,lO-phenanthroline, ethylenediamine,
o-phenylenediamine, diphenylamine, pyridine, 4-cyanopyridine, triphenylphosphine,
triphenylphosphine oxide, or 1,2-bisdiphenylarsinoethane), (C6F5)HgL2 (L = di-2-pyridylamine), and [(C6F5)2Hg]L (L = bisdiphenylphosphinomethane or bisdiphenylarsinomethane)
have been prepared, and their constitution, solution stabilities, and structures studied, together with those of the known complexes (C6F5)2HgL (L = 2,2'-
bipyridyl, 1,lO-phenanthroline, or 1,2-bisdiphenylphosphinoethane). Coordination of
triphenylarsine oxide to bispentafluorophenylmercury in solution has also been detected, but the complex could not be isolated." name="eprints.abstract" />
<meta content="1971" name="eprints.date" />
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<meta content="Australian Journal of Chemistry" name="eprints.publication" />
<meta content="24" name="eprints.volume" />
<meta content="3" name="eprints.number" />
<meta content="489-499" name="eprints.pagerange" />
<meta content="10.1071/CH9710489" name="eprints.id_number" />
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<meta content="* Part X, Aust. J. Chem., 1970, 23, 1275.
t Chemistry Department, Monash University, Clayton, Vic. 3168.
Coates, G. E., Green, M. L. H., and Wade, K., &quot;Organometallic Compounds.&quot; Vol. I.
(Eds. G. E. Coates and K. Wade.) pp. 164,168,132-141,146. (Methuen: London 1967.)
EmelBus, H. J., and Lagowski, J. J., J. chem. Soc., 1959, 1497; Downs, A. J., J. inorg.
nucl. Chem., 1964, 26, 41.
Chambers, R. D., Coates, G. E., Livingstone, J. G., and Musgrave, W. K. R., J. chem.
SOC., 1962, 4367.
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1966, 106.
Connett, J. E., and Deacon, G. B., J. chem. Soc. (C), 1966, 1058.
Powell, H. B., and Lagowski, J. J., J. chem. Soc. (A), 1966, 1282.
Deacon, G. B., and Felder, P. W., Aust. J. Chem., 1966, 19, 2381.
Chambers, R. D., Drakesmith, F. G., Hutchinson, J., and Musgrave, W. K. R., Tetrahedron
Lett., 1967, 1705; Bregadze, V. I., and Okhlobystin, 0. Yu., Dokl. Akad. Nauk SSSR,
1967, 177, 347; Zakharkin, L. I., and Podvisotskaya, L. S., J. gen. Chem. USSR, 1969,
39, 896; Izv. Akad. Nauk SSSR, Ser. Khim., 1968, 681.
Canty, A. J., and Deacon, G. B., Aust. J. Chem., 1968, 21, 1757.
lo Deacon, G. B., and Canty, A. J., Inorg. nucl. Chem. Lett., 1969, 5, 183.

11 Clark, R. J. H., Spectrochim. Acta, 1965, 21, 955.
l2 Konig, E., Madeja, K., and Watson, K. J., J. Am. chem. Soc., 1968, 90, 1146.
13 Schilt, A. A., and Taylor, R. C., J. inorg. nucl. Chem., 1959, 9, 211.
14 Inskeep, R. G., J. inorg. nucl. Chem., 1962, 24, 763.
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17 POPOVA, . I., Marshall, J. C., Stute, F. B., and Person, W. B., J. Am. chem. Soc., 1961,
83, 3586.
18 Farha, F., and Iwamoto, R. T., Inorg. Chem., 1965, 4, 844.
19 Brown, T. L., and Kubota, M., J. Am. chem. Soc., 1961, 83, 4175; Coerver, H. J., and
Curran, C., J. Am. chem. Soc., 1958, 80, 3622; Rouschias, G., and Wilkinson, G., J.
chem. Soc. (A), 1968, 489; Walton, R. A., Q. Rev. chem. Soc., 1965, 19, 126.
20 Halman, M., and Pinchas, S., J. chem. Soc., 1958, 3264; Daasch, L. W., and Smith, D. C.,
Analyt. Chem., 1951, 23, 853.
z1 Cotton, F. A., Barnes, R. D., and Bannister, E., J. chem. Soc., 1960, 2199; Sheldon, J. C.,
and Tyree, S. Y., J. Am. chem. Soc., 1958, 8G, 4775.
2Woodgame, D. &amp;I. L., and Cotton, F. A., J. chem. Soc., 1961, 2298, 3735.

23 Phillips, D. J., and Tyree, S. Y., J. Am. chem. Soc., 1961, 83, 1806.
24 Deacon, G. B., and Green, J. H. S., Chemy Ind., 1965, 1031; Spectrochim. Actu (A),
1968, 24, 845.
Powell, D. B., and Sheppard, N., Spectrochim. Actu, 1961, 17, 68.
26 Newman, G., and Powell, D. B., J. chem. Soc., 1961,477; Brodersen, K., 2. unorg. Chem.,
1959, 298, 142; Iwamoto, T., Inorg, chim. Acta, 1968, 2, 269.
27 Barvinok, M. S., and Bukhareva, I. S., Rum. J. inorg. Chem., 1965, 10, 464.
Is Marks, D. R., Phillips, D. J., and Redfern, J. P., J. chem. Soc. (A), 1967, 1464.
29 Duff, E. J., J. chem. Soc. (A), 1968, 434.
ao Baxter, J. N., Cymerman-Crsig, J., end wi!!is, J. B., J. chem. SK., 1955, 669.
Sabatini, A,, and Califano, S., Spectrochim. Actu, 1960, 16, 677.
S2 Cotton, F. A,, &quot;The Infrared Spectra of Transition Metal Complexes&quot; in &quot;Modern
Coordination Chemistry.&quot; (Eds. J. Lewis and R. G. Wilkins.) p. 363. (Interscience:
New York 1960); Chatt, J., Duncanson, L. A., and Venanzi, L. M., J. chem. Soc.,
1965, 4461; 1956, 2712.

ss Canty, A. J., and Gatehouse, B. M., unpublished data.
84 IkIoWhinnie, W. R., and Miller, J. D., Adv. inorg. Chem. Radiochem., 1969, 12, 135.
S5 Noltes, J. G., and Van den Hurk, J. W. G., J. organomet. Chem., 1965, 3, 222.
SB Nakamoto, K., J. phys. Chem., 1960, 64, 1420.

Sill&amp;, L. G., and Martell, A. E., &quot;Stability Constants.&quot; Special Publication No. 17.
(Chernicrl,! Society: London 1964.)
Grdenic, D., Q. Rev. chem. Soc., 1965, 19, 303.
39 Kunchur, N. R., and Mathew, M., Chem. Commun., 1966, 71.
40 Branden, C.-I., Acta chem. scad., 1963, 17, 1363.
41 Douglas, J. E., and Wilkins, C. J., Inorg. chim. Acta, 1969, 3, 635.
42 E.g. Goodgame, IM., J. chem. Soc. (A), 1966, 63.


4a McPhail, A. T., and Sim, G. A,, Chem. Commun., 1966, 21.
44 Kulpe, S., 2. anorg. Chem., 1967, 349, 314.
46 Barbieri, R., Faraglia, G., Giustiniani, M., and Roncucci, L., J, inorg. nucl. Chem., 1964,
26, 203.
46 Eimh~nuS, ., BE&amp; Xat.th;eu, J. P., C. .I. habd. 86a1i~A. cad. Sci., Paris, i960, %i,9 38; Miiier,
F. A., Carlson, G. L., Bentley, F. F., and Jones, W. H., Spectrochim. Acta, 1960,
16, 135.
47 Coates, G. E., and Ridley, D., J. chem. Sac., 1964, 166.
48 Deacon, G. B., Green, J. H. S., and Harrison, D. J., Spectrochim. Acta (A), 1968,24, 1921.
49 Challenger, F., and Wilson, V. K., J. chem. Soc., 1927, 209

50 Bannister, E., and Cotton, F. A., J. chem. Soc., 1960, 1878.
61 Ca88, F. H., and Brennan, J. A., J. org. Chem., 1954, 19, 919; Calf, G. E., and Samuel,
E. L., Aust. J. Chem., 1963, 16, 833.
5a Deacon, G. B., Albrecht, H. B., and Osborne, M. J., Imorg. mucl. Chem. Lett., 1969,5, 985." name="eprints.referencetext" />
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<meta content="The oomplexes (C6F5)2HgL (L = 4,4'-dimethyl-2,2'-bipyridyl, 2,2'-biquinolyl, 2,2':6',2&quot;-terpyridyl, 2,4,7,9-tetramethyl-1,lO-phenanthroline, ethylenediamine,
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    <h1 class="ep_tm_pagetitle">Organomercury Compounds XI. Some Coordination Derivatives of Bispentafluorophenylmercury</h1>
    <p style="margin-bottom: 1em" class="not_ep_block"><span class="person_name">Canty, A.J.</span> and <span class="person_name">Deacon, G.B.</span> (1971) <xhtml:em>Organomercury Compounds XI. Some Coordination Derivatives of Bispentafluorophenylmercury.</xhtml:em> Australian Journal of Chemistry, 24 (3). pp. 489-499. ISSN 0004-9425</p><p style="margin-bottom: 1em" class="not_ep_block"></p><table style="margin-bottom: 1em" class="not_ep_block"><tr><td valign="top" style="text-align:center"><a href="http://eprints.utas.edu.au/2821/1/AustJ1971_2C_489.pdf"><img alt="[img]" src="http://eprints.utas.edu.au/style/images/fileicons/application_pdf.png" border="0" class="ep_doc_icon" /></a></td><td valign="top"><a href="http://eprints.utas.edu.au/2821/1/AustJ1971_2C_489.pdf"><span class="ep_document_citation">PDF</span></a> - Full text restricted - Requires a PDF viewer<br />643Kb</td><td><form method="get" accept-charset="utf-8" action="http://eprints.utas.edu.au/cgi/request_doc"><input value="4013" name="docid" accept-charset="utf-8" type="hidden" /><div class=""><input value="Request a copy" name="_action_null" class="ep_form_action_button" onclick="return EPJS_button_pushed( '_action_null' )" type="submit" /> </div></form></td></tr></table><p style="margin-bottom: 1em" class="not_ep_block">Official URL: <a href="http://www.publish.csiro.au/nid/51/paper/CH9710489.htm">http://www.publish.csiro.au/nid/51/paper/CH9710489.htm</a></p><div class="not_ep_block"><h2>Abstract</h2><p style="padding-bottom: 16px; text-align: left; margin: 1em auto 0em auto">The oomplexes (C6F5)2HgL (L = 4,4'-dimethyl-2,2'-bipyridyl, 2,2'-biquinolyl, 2,2':6',2"-terpyridyl, 2,4,7,9-tetramethyl-1,lO-phenanthroline, ethylenediamine,&#13;
o-phenylenediamine, diphenylamine, pyridine, 4-cyanopyridine, triphenylphosphine,&#13;
triphenylphosphine oxide, or 1,2-bisdiphenylarsinoethane), (C6F5)HgL2 (L = di-2-pyridylamine), and [(C6F5)2Hg]L (L = bisdiphenylphosphinomethane or bisdiphenylarsinomethane)&#13;
have been prepared, and their constitution, solution stabilities, and structures studied, together with those of the known complexes (C6F5)2HgL (L = 2,2'-&#13;
bipyridyl, 1,lO-phenanthroline, or 1,2-bisdiphenylphosphinoethane). Coordination of&#13;
triphenylarsine oxide to bispentafluorophenylmercury in solution has also been detected, but the complex could not be isolated.</p></div><table style="margin-bottom: 1em" border="0" cellpadding="3" class="not_ep_block"><tr><th valign="top" class="ep_row">Item Type:</th><td valign="top" class="ep_row">Article</td></tr><tr><th valign="top" class="ep_row">Subjects:</th><td valign="top" class="ep_row"><a href="http://eprints.utas.edu.au/view/subjects/259901.html">250000 Chemical Sciences &gt; 259900 Other Chemical Sciences &gt; 259901 Organometallic Chemistry</a></td></tr><tr><th valign="top" class="ep_row">Collections:</th><td valign="top" class="ep_row">UNSPECIFIED</td></tr><tr><th valign="top" class="ep_row">ID Code:</th><td valign="top" class="ep_row">2821</td></tr><tr><th valign="top" class="ep_row">Deposited By:</th><td valign="top" class="ep_row"><span class="ep_name_citation"><span class="person_name">Prof Allan J Canty</span></span></td></tr><tr><th valign="top" class="ep_row">Deposited On:</th><td valign="top" class="ep_row">11 Jan 2008 09:50</td></tr><tr><th valign="top" class="ep_row">Last Modified:</th><td valign="top" class="ep_row">18 Jan 2008 13:35</td></tr><tr><th valign="top" class="ep_row">ePrint Statistics:</th><td valign="top" class="ep_row"><a target="ePrintStats" href="/es/index.php?action=show_detail_eprint;id=2821;">View statistics for this ePrint</a></td></tr></table><p align="right">Repository Staff Only: <a href="http://eprints.utas.edu.au/cgi/users/home?screen=EPrint::View&amp;eprintid=2821">item control page</a></p>
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